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Beilstein J. Org. Chem. 2017, 13, 800–805, doi:10.3762/bjoc.13.80
Graphical Abstract
Figure 1: pKa values for N-aminopyridinium cation hydrogen atoms according to DFT M06-2X 6-31+G(d,p) calculat...
Scheme 1: H/D exchange of N-aminopyridinium salts 1a–c and their reaction with acetylenes.
Scheme 2: Possible pathways for the formation of 8.
Figure 2: Relative stability of 3-CO2Et-substituted dihydropyrazolo[1,5-a]pyridines by the M06-2X 6-31+G(d,p)...
Scheme 3: Synthesis of deutero 1,2,4-triazolo[1,5-a]pyridines.